An Agglomerate Model for the Rationalisation of MCFC Cathode Degradation

B. Bozzini[1], S. Maci[1], I. Sgura[2], R. Lo Presti[3], and E. Simonetti[3]
[1]Dipartimento di Ingegneria dell’Innovazione, Università del Salento, Lecce, Italy
[2]Dipartimento di Matematica, Università del Salento, Lecce, Italy
[3]ENEA Casaccia, Dipartimento TER, Centro Ricerche Casaccia, S. Maria di Galeria, Roma, Italy

This paper describes the numerical modeling of a key material-stability issue within the realm of Molten Carbonate Fuel Cells (MCFC). The model describes the morphological and attending electrocatalytic evolution of porous NiO electrodes and is apt to predict electrochemical observables that can be recorded during Fuel Cell operation. The model has been validated with original experimental data measured with different laboratory-scale system.

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