Numerical Modeling of the Electrochemical Behaviour of Metallic Alloys based upon Experimental Measurements at the Macro- and Microscale
H. Krawiec1, V. Vignal2, and R. Akid3
1AGH University of Science and Technology, Krakow, Poland
2ICB, UMR 5209 CNRS, Université de Bourgogne, Dijon, France
3Sheffield Hallam University, Sheffield, UK
Micro capillary-based techniques allow the interrogation of single metallurgical sites and are therefore becoming increasingly popular for the investigation of the electrochemical behavior of metallic phases and non-metallic heterogeneities in alloys. This study was carried out to assess the differences between current measurements made using a 'closed' micro-capillary system (the electrochemical ...
M. Hackert, G. Meichsner, and A. Schubert[1,2]
Micromanufacturing Technology, Chemnitz University of Technology, Chemnitz, Germany
Fraunhofer Institute of Machine Tools and Forming Technology, Chemnitz, Germany
Electrochemical Machining with a closed electrolytic free jet is a special procedure to generate complex micro structures by help of anodic dissolution. The work piece shape is fabricated by supplying an electrolytic current through an electrolyte jet ejected from a small nozzle. In this study COMSOL Multiphysics is used to simulate the electric current density in the jet and the dissolution ...
M. Hackert-Oschätzchen, S. F. Jahn, and A. Schubert
Chemnitz University of Technology
The principle of electrochemical machining (ECM) is the anodic dissolution of a metallic workpiece at the interface to a liquid ionic conductor under the influence of electric charge transport. This erosion principle works independently from the mechanical hardness of the workpiece and is free of mechanical forces. The design of electrochemical machining processes is still performed ...
Y. Wang, D. Uwe Sauer
Electrochemical Energy Conversion and Storage Systems, Institute for Power Electronics and Electrical Drives (ISEA), RWTH Aachen University, Aachen, Germany
HTPEM fuel cells are considered to be the next generation fuel cells. The electrochemical kinetics for electrode reactions are enhanced by using PBI membrane at an operation temperature between 160-180 °C comparing to LTPEM fuel cells. But starting HTPEM fuel cells from room temperature to an operation temperature is a challenge. In this work, using preheated air to heat up the fuel cells ...
Kinetic Investigation of a Mechanism for Generating Microstructures on Polycrystalline Substrates Using an Electroplating Process
T. Soares, H. Mozaffari, H. Reinecke
Universität Freiburg, Freiburg im Breisgau, BW, Germany
Hochschule Furtwangen, Tuttlingen, BW, Germany
The purpose of this study is to understand the growth mechanism of copper (Cu) films on a Cu-Zn system substrate with a pre-defined pattern. The pattern was defined by conducting a selective etching process on a two-phase polycrystalline substrate. As a result of this process, there were etched regions correspondent to beta-phase crystals and quasi non-etched regions that belong to alpha-phase ...
K. Daneshvar, A. Fantino, C. Cristiani, G. Dotelli, R. Pelosato, M. Santarelli
Politecnico di Milano, Dipartimento di Chimica, Materiali e Ingegneria Chimica “G. Natta”, Milano, Italy
Politecnico di Torino, Dipartimento di Energetica, Torino, Italy
A 2D isothermal axisymmetric model of an anode-supported Solid Oxide Fuel Cell (SOFC) has been developed. Also a parametric analysis to find the effect of important parameters on the cell performance has been done. This simulation has been carried out at 1 atm and 1073 K. The PEN materials are traditional ones: Ni-YSZ/YSZ/LSM-YSZ as anode, electrolyte and cathode respectively.The developed model ...
E. M. Fontes
Catella Generics AB
Computational mathematical modeling has allowed scientists and engineers to perform better, faster, and more economical virtual experiments. Through mathematical modeling, an application expert can simulate performance characteristics during different operating conditions and thereby accelerate the pace of understanding new electrochemical system in relation to specific application ...
National University of Tainan
This presentation considers multiphysics modeling of Fuel Cells. The presentation introduces the fundamentals of Fuel Cells, the need for computer aided modeling of them, different difficulties and hindrances one encounters when modeling Fuel Cells, and methods to overcome these difficulties when modeling them. A good understanding and thorough discussion on different types of Fuel Cells ...
B. Morel1, P. Namy2, C. Belhomme1, and I. Crassous3
1Comurhex, Pierrelatte, France
2SIMTEC, Grenoble, France
3LI2C, Paris, France
Modeling electrolysers is a challenge because of the strong coupling between electrical, thermal and CFD equations. Indeed the electrical conductivity of the electrolyte varies with the temperature, which in turn depends on the heat dissipated by the Joule effect and anode over-voltage.In the present study, the fluid velocity values are computed near the electrodes using a diphasic level set ...
L. Lam, and R. Darling
University of Washington
Many physical systems contain sequential modes of operation. The sequence is one-way and switching between modes is dependent upon specific internal parameters of the system itself. While COMSOL provides the flexibility to perform time-domain simulation and time-based modifications of boundary conditions, simulating sequential systems based upon internal physical variables in COMSOL can be a ...