R. Hamou, P. Biedermann, M. Rohwerder, and A. Blumeneau
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
The present work focuses on modeling a new experimental technique: Scanning Electro-chemical Potential Microscopy (SECPM), which is used to probe the potential profile of the electric double layer (EDL). We used an electrostatic approach to compute the EDL potential measured within the metallic probe. Also, we investigated the effect of the interaction of the electrode/probe double layers on the ...
K. Song, and H. Knickle
Department of Chemical Engineering, University of Rhode Island, Kingston Rhode Island, USA
In this paper we present a study of the time dependent analysis of a metal hydride bed (MHB) which provides constant flow to a fuel cell at required power loading and pressure. The hydrogen gas phase pressure, the hydrogen concentration in the metal hydride and the hydrogen desorption rate are consider as key variables in this study. Both the space scale and time scale analysis are performed. ...
Renewable Energy RD Center, Chung-Hsin Electric & Machinery, Taiwan
Proton exchange membrane fuel cells (PEMFCs) were investigated using COMSOL Multiphysics with the AC/DC Module and Chemical Engineering Module. Simulation may be used to increase the performance while decreasing the cost of the catalyst later (CL). Experimental validation of single and multi-layer CL was performed for varied PBI electrolyte content. The validated model was used to investigate the ...
Optimisation of the Electrochemical Instrumentation of a Wear Simulator through Finite Element Modelling
Déforge, D.1, 2, Ponthiaux, P.2, Wenger, F.2, Lina, A.1, Ambard, A.1
1 Electricité de France (EDF) R&D, Chemistry and corrosion group, Les Renardières, Moret sur Loing cedex, France
2 Laboratory LGPM, Ecole Centrale Paris, Chatenay-Malabry cedex, France
Stainless steels are often used in nuclear power plants due to their good corrosion resistance. This good behaviour is due to an oxide film which forms on their surface and insulates them from the corrosive media. Sometimes, flow-induced vibrations can however lead to some contacts between the components, and thus to the degradation of this oxide film. The mechanical removal leads to an increase ...
N. Godino1, F. J. del Campo2, and F. X. Muñoz1
1Instituto de Microelectrónica de Barcelona, IMB-CNM-CSIC, Barcelona, Spain
2Institut de Biotecnologia i Biomedicina "Vicent Pallar Palasi", Universitat Autónoma de Barcelona, Barcelona, Spain.
Microfluidics enables the miniaturization and integration of sensors into advanced analytical devices. Electrochemical detection is currently one of the preferential techniques of use in microfluidic devices due to its sensitivity, low cost and compatibility with new microfabrication techniques. In this work, we first model the electrochemical response of a set of microband electrodes placed ...
G. Ganzer, W. Beckert, T. Pfeifer, and A. Michaelis
The high thermal stability and fast start-up behavior make micro-tubular solid oxide fuel cells (SOFCs) a promising alternative for small-scale, mobile power devices in the range of some Watts. To understand the transport phenomena inside a single micro-tubular SOFC, a 2-D, axi-symmetric, non-isothermal model, performed in COMSOL Multiphysics® 4.2, has been developed. Due to long current path ...
A. K. R. Paul, K. S. Gandhi, and A. K. Shukla
 Central Electrochemical Research Institute – Madras Unit, CSIR Complex, Taramani, Chennai, Tamil Nadu, India
 Department of Chemical Engineering, Indian Institute of Science, Bangalore , Karnataka, India
 Solid State & Structural Chemistry Unit, Indian Institute of Science, Bangalore , Karnataka, India
Direct borohydride fuel cells (DBFCs) use sodium borohydride (NaBH4) as fuel and hydrogen peroxide (H2O2) as an oxidant. A mathematical model encompassing mass balance of ionic species in different regions of the DBFC is developed. Both the oxidation of sodium borohydride and reduction of hydrogen peroxide are assumed to obey Tafel kinetics. This is combined with boundary conditions ...
Amimer, A.1, 2, Mandin, P.3, Lincot, D.3, Horner, O.1
1 EDF R&D, Département MMC, Moret-sur-Loing, France
2 Ecole Nationale Supérieure de Chimie de Paris, Paris, France
3 Ecole Nationale Supérieure de Chimie de Paris, UMR 7575, Paris, France
Flow Accelerated Corrosion (FAC) of carbon steel has been studied world-wide for more than twenty years and is now fairly well understood. The influence of several parameters like water chemistry (pH, dioxygen content), temperature, hydrodynamic or mass transfer conditions (flow velocity, geometry) and steel composition on the corrosion kinetics has been demonstrated both theoretically (“Berge ...
J. Caire, A. Bouh, and E. Guilminot
LEPMI, UMR 5631, INPG - CNRS, Saint Martin d’Hères, France
EPCC, Arc'Antique, Nantes, France
Restoration of archaeological materials from oceans is a major activity of Arc’ Antique. Organic materials such as wood, tissues, leathers, papers and ceramics found in sea water are always impregnated with salts. Rinsing such archaeological objects with pure water to extract the salts takes too long, so electrophoresis was used to improve the salt extraction. The objective of this ...
P. Fodor, and J. D'Alessandro
Dept. of Physics
Cleveland State University
In this work a miniaturized fuel cell design based on microchannels, into which the liquid fuel and oxidizer streams are fed through T shaped connectors, is optimized for improved fuel usage. This particular design exploits the laminar nature of the fluid flow at small Reynolds numbers to keep the fuel and oxidizer confined in the vicinity of the corresponding electrodes without the need of a ...