Numerical and Experimental Investigation of Natural Convection Flow of (Sub-) and (Super-) Critical CO2 in Aqueous Phase
R. Khosrokhavar, G. Elsinga, R. Farajzadeh, H. Bruining
Delft University of Technology, Delft, The Netherland
Shell International Global Solutions, Amsterdam, The Netherland
Optimal storage of carbon dioxide (CO2) in aquifers requires dissolution in the aqueous phase. Transfer of CO2 from the gas phase to the aqueous phase or oil phase would be slow if it were only driven by diffusion. Dissolution of CO2 in brine (oil) forms a mixture that is denser than the original brine. This causes a local density increase, which induces natural convection currents accelerating ...
J. Bouhattate, E. Legrand, A. Oudriss, S. Frappart, J. Creus, and X. Feaugas
Laboratoire d’Etude des Matériaux en Milieu Agressif, LEMMA, Bat. Marie Curie, La Rochelle, France
To understand a metal susceptibility to Hydrogen Embrittlement (HE), it is important to quantify the diffusion of hydrogen through a metallic membrane. Electrochemical permeation tests are the most common methods for experimentally determining the diffusion coefficient of a metal. However the parameters directly accessible from experiments are the time required for a stream to be observed and ...
Modeling and Simulation of Dielectric Barrier Discharge Plasma Reactor for Nitrogen Fixation Reaction
B.S. Patil, Q. Wang, V. Hessel, J. Lang
Eindhoven University of Technology, Eindhoven, The Netherlands
Micro Flow Chemistry and Process Technology, Eindhoven University of Technology, Eindhoven, The Netherlands
Innovation Management, Verfahrenstechnik & Engineering, Evonik Industries AG, Hanau-Wolfgang, Germany
Fixed nitrogen is used in many forms ranging from nitric acid to hydrogen cyanide and is used as such for industrial applications. The reactions to produce these products are highly endothermic and favored by high-temperature processing. The most basic route of chemically fixing nitrogen is the direct reaction of nitrogen and oxygen. However, the major challenge is to supply very high ...
B. Castro-Dominguez, R. Ma, A. G. Dixon, Y. H. Ma
Chemical Engineering Department, Worcester Polytechnic Institute, Worcester, MA, USA
The optimization of operating conditions in multitube membrane modules is highly complex. The multiple physics and irregular geometries involved create a challenge for predicting their behavior. This work analyzes the performance of H2 purification through a module containing seven membranes. Using experimental parameters, a 3-D model was devised, specifying the membrane as a reacting boundary ...
Boundary conditions in multiphase, porous media, transport models of thermal processes with rapid evaporation
A. Datta, and A. Halder
Biological and Environmental Engineering, Cornell University, Ithaca, New York, USA
In modeling of thermal processing of biological materials with rapid evaporation, it is critical to provide boundary conditions consistent with the phenomena happening at the surface to accurately predict spatial temperature and moisture content for quality and safety assurance. Boundary conditions in a mathematical model are as important as governing equations itself and describe how the heat ...
Development of a Multiphase, Multispecies Droplet Evaporation Model for Optimization of Desiccation Preservation Techniques
A. Sinkevich, S. Bhowmick , M. Raessi
University of Massachusetts Dartmouth, North Dartmouth, MA, USA
Biopreservation deals with the protection and storage of complex biologics such as proteins, lipids, and recently, mammalian cells. One preservation method, known as lyopreservation, involves placing a biologic inside a water droplet with some type of sugar excipient (sucrose, trehalose, etc.) and drying the solution convectively. We are currently developing a model that couples the two-phase ...
A Theoretical Model for the Control of Color Degradation and Microbial Spoilage Occurring in Food Convective Drying
S. Curcio, M. Aversa
University of Calabria, Department of Engineering Modeling, Rende, Cosenza, Italy
The aim of this work was the development of a predictive model aimed at identifying a proper control strategy of food drying process. In particular, it was intended to determine the effect of operating conditions both on the color degradation, chosen as a reference quality parameter, and on the microbial spoilage occurring during potatoes drying. A transport model, accounting for the ...
F. Mansilla, L. Voisin 
Advanced Mining Technology Center, Chile University, Santiago, Chile
Department of Mining Engineering, Advanced Mining Technology Center, Chile University, Santiago, Chile
Throughout history, the copper pyrometallurgical processes have been carried out mostly in discontinuous or batch systems. In recent decades new continuous technologies have been developed but focused only on Smelting and Converting stages leaving aside the Refining one. In 2002 a novel technology was proposed by the Department of Mining Engineering of Chile University which consists in two ...
L. Nespoli, M. Bianchi Janetti, F. Ochs
Politecnico di Milano, Milan, Italy
University of Innsbruck, Innsbruck, Austria
A model for the conjugate simulation of heat and moisture transfer inside porous materials and fluid domains is implemented in COMSOL Multiphysics®. The results of this model are compared with those obtained through a simplified approach: the line-source approach. The models are both validated with experimental data and with numerical results from other authors. On the one hand the conjugate ...
Study of a Self Heating Process of Tetrafluoroethylene by the Exothermic Dimerization Reaction to Octafluorocyclobutane
M. Beckmann-Kluge, H. Krause, V. Schröder, A. Acikalin, and J. Steinbach
Federal Institute for Materials Research and Testing, Berlin, Germany
Technical University Berlin, Berlin, Germany
The self heating process of Tetrafluoroethylene caused by an exothermic dimerization reaction was studied. The heat of reaction can lead to a thermal explosion by the decomposition of the Tetrafluoroethylene. Different reaction kinetics, including multistep kinetics, were used to describe the mass balance. The COMSOL Chemical Engineering Module was used to perform the simulation which was ...