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Cyclic Voltammetry

Cyclic voltammetry is a common analytical technique for investigating electrochemical systems. In this method, the potential difference between a working electrode and a reference electrode is swept linearly in time from a start potential to a vertex potential, and back again. The current-voltage waveform, called a voltammogram, provides information about the reactivity and mass transport ...

Mass Transport Analysis of a High Temperature PEM Fuel Cell

This model example investigates the transport of reactants and water in a high temperature PEMFC. The model includes mass and momentum transport phenomena in the flow channels, gas diffusion layers (GDLs), and porous electrodes, as well as electrochemical currents in the GDLs, the porous electrodes, and the polymer membrane.

Current Density Distribution in a Solid Oxide Fuel Cell

This model presents a study of the current density distribution in a solid oxide fuel cell (SOFC). The model includes the full coupling between the mass balances at the anode and cathode, the momentum balances in the gas channels, the gas flow in the porous electrodes, the balance of the ionic current carried by the oxide ion, and a balance of electronic current. A truly large number of ...

Species Transport in the Gas Diffusion Layers of a PEM

This example focuses on the species transport within the gas diffusion layers (GDLs) of a proton exchange membrane (PEM) fuel cell. The geometry models a cell with two adjacent flow channels of different pressures, a situation that may occur in a cell with serpentine flow channels, or in a cell using an interdigitated flow field design. The model uses current balances, mass transport equations ...

Fuel Cell with Serpentine Flow Field

This example models the flow and mass transport in the channels and the gas diffusion layer (GDL) of a polymer electrolyte fuel cell. The cathode electrode reaction is modeled as a boundary condition, where the local current density depends on the overpotential and the local oxygen concentration. The overpotential is solved for along the cathode boundary by the use of a distributed DAE. The ...

Liquid-Cooled Lithium-Ion Battery Pack

This model simulates a temperature profile in a number of cells and cooling fins in a liquid-cooled battery pack. The model solves in 3D and for an operational point during a load cycle. A full 1D electrochemical model for the lithium battery calculates the average heat source.

Single Particle Model of a Lithium-Ion Battery

An isothermal single particle model formulation for a lithium-ion battery is presented in this work. The single particle model is a simplification of the 1D formulation for a lithium-ion battery along with a few assumptions. The model is typically valid for low-medium current scenarios. Note that validity of the assumptions and applicability of the single particle model also depends on the ...

Voltammetry at a Microdisk Electrode

Voltammetry is modeled at a microelectrode of 10um radius. In this common analytical electrochemistry technique, the potential at a working electrode is swept up and down and the current is recorded. The current-voltage waveform ("voltammogram") gives information about the reactivity and mass transport properties of the analyte. Microelectrodes are popular in electroanalysis because they ...

Vanadium Redox Flow Battery

This 2D example of a vanadium flow battery demonstrates how to couple a secondary current distribution model for an ion-exchange membrane to tertiary current distribution models for two different free electrolyte compartments of a flow battery. The *Ion-Exchange Membrane* boundary node specifies a boundary condition where the flux of ions is continuous, but where the electrolyte potential is ...

1D Lithium-Ion Battery Impedance Model

The impedance of a lithium-ion battery cell with a negative LTO and positive NCA electrode is modeled for harmonic perturbations between 10 mHz to 1000 Hz. The model incorporates an additional double-layer current at the conductive material in the positive electrode. The impedance of each electrode is also possible to investigate versus a reference electrode located in the middle of the ...