Screening Effects in Probing the Electric Double Layer by Scanning Electrochemical Potential Microscopy
R.F. Hamou, P.U. Biedermann, A. Erbe, and M. Rohwerder
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
A computational method is developed to study probing the electric double layer by Scanning Electrochemical Potential Microscopy. The model is based on a modified Poisson- Boltzmann equation, which takes into account steric effects. We investigated the effect of metallic apex protrusion and the Open Circuit Potential (OCP) of the tip on the probed potential. A clear electrostatic screening effect ...
M. Hackert, G. Meichsner, and A. Schubert[1,2]
Micromanufacturing Technology, Chemnitz University of Technology, Chemnitz, Germany
Fraunhofer Institute of Machine Tools and Forming Technology, Chemnitz, Germany
Electrochemical Machining with a closed electrolytic free jet is a special procedure to generate complex micro structures by help of anodic dissolution. The work piece shape is fabricated by supplying an electrolytic current through an electrolyte jet ejected from a small nozzle. In this study COMSOL Multiphysics is used to simulate the electric current density in the jet and the dissolution ...
Modelling of a 5 Cell Intermediate Temperature Polymer Electrolyte Fuel Cell (IT-PEFC) Stack: Analysis of Flow Configuration and Heat Transfer
A.S. Chandan, A. Mossadegh Pour, R. Steinberger-Wilckens
Centre for Hydrogen and Fuel Cell Research, University of Birmingham, Birmingham, United Kingdom
University of Birmingham, Birmingham, United Kingdom
Polymer Electrolyte Fuel Cells (PEFCs) are a key technology in the advancement of society towards a low carbon future, in particular for use within the automotive sector. PEFCs are advantageous due to their low operating temperature (60-80 deg.C), quick start up times and responsiveness to load change. However, the requirement for expensive platinum, difficulty of water management and heat ...
F. A. Daniels, D. J. L. Brett, A. R. Kucernak, and C. Attingre
University College London, London, UK
Imperial College London, London, UK
Polymer electrolyte membrane (PEM) fuel cells have significant potential as a source of clean, efficient energy production. This study presents a three-dimensional, non-isothermal, fully-coupled model of a PEM fuel cell with printed circuit board current collectors. The effect of the current collector design on transport phenomena and consequent cell performance is investigated. The model ...
S. Mackintosh, J. Rodgers, S.P. Blythe
Lifescan Scotland, Inverness, Scotland
This paper describes the modeling of a blood glucose sensor using COMSOL Multiphysics. Chemical species interaction and diffusion, coupled with electrochemical oxidation of multiple blood species produced a powerful working model used in developing and refining a range of blood glucose sensors for the commercial market.
M. Hackert, G. Meichsner, and A. Schubert
Chair Micromanufacturing Technology, Faculty of Mechanical Engineering, Chemnitz University of Technology, Chemnitz, Germany
Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany
Jet Electrochemical Machining (Jet-ECM) is an unconventional procedure using localized anodic dissolution for micromachining. An increasing of the electrolyte temperature will lead to an increase of the electrical conductivity of the electrolyte by about 30% and to a reduction of the dynamic viscosity of the electrolyte by about 25 %. Both will improve the process. Therefore a Jet-ECM tool ...
I. Sgura, F. Zarcone, and B. Bozzini
Dipartimento di Matematica, Università del Salento, Lecce, Italy
Brindisi Fuel Cell Durability Laboratory, Facoltà di Ingegneria Industriale, Università del Salento, Brindisi, Italy
Corrosion and contact ohmic resistance of the stainless steel current collectors in molten carbonates is one of the greatest obstacles to widespread application of molten carbonate fuel cells (MCFC). We simulate the variation of material parameters values, accounting for the impact of corrosion of the metallic current collectors on the performance of the porous cathode. Furthermore, we couple a ...
R. Pushpangadan, A. Soman, Arundas R., N. G. Thoppan, S. P. Duttagupta
Department of Electrical Engineering, Indian Institute of Technology Bombay, Mumbai, Maharashtra, India
College of Engineering, Munnar, Kerala, India
PEM fuel cells are very promising for portable applications. A key component of fuel cell is the flow field plate through which hydrogen will reach the anode, oxygen will reach the cathode and electron collection. Flow field plate made of silicon is not a good electrical conductor , so electrical contacts has to be attached to the Gas Diffusion Layer (GDL) for taking the power to outside ...
A. E. Khabbazi, A.J. Richards, and M. Hoorfar
School of Engineering, UBC Okanagan, Kelowna, BC Canada, Canada
Using COMSOL Multiphysics 3.5, a numerical model has been developed to determine the effect of the channel geometry and electrode configuration on cell performance based on polarization curves. The Butler-Volmer equation was implemented to determine the reaction rates at the electrodes. The Conductive Media DC module is used to model the electric fields within the fuel cell.
Modeling a Non-Flooding Hybrid Polymer Electrolyte Fuel Cell and Related Diffusion-Migration-Reaction Systems
B.E. McNealy, J.L. Hertz
University of Delaware, Newark, DE, USA
Introduction: Understanding the mass and charge transport behavior of heterogeneous systems that include diffusion, migration, and reaction of ions is important in fuel cells, batteries, and other electrochemical applications. Here, a numerical model for charged species transport and reaction has been developed to simulate the electrochemical behavior of a novel type of “non-flooding” hybrid ...