Numerical Simulation of Carbon Steel Corrosion Exposed to Flowing NaCl Solutions Through an Annular Duct - new
A. Soliz, K. Mayrhofer, L. Caceres
Department of Interface Chemistry & Surface Engineering, Max-Planck-Institut für Eisenforschung, Düsseldorf, Germany
Department of Chemical Engineering, University of Antofagasta, Antofagasta, Chile
A three-dimensional mathematical model under stationary conditions have been established to understand the corrosion of carbon steel cylindrical samples immersed in flowing NaCl solution through an annular duct. The migration, diffusion and convection mass transfer mechanisms were solved using the Nernst–Planck equation coupled to the Navier-Stokes equation. A corrosion model based on the mixed ...
J. H. Al-Smail 
 King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia
We develop a porosity-optimization problem to improve the electrochemical reactions taking place in hydrogen fuel cells. We introduce a mathematical model, which involves a system of conservation laws defined in a porous space domain. Our goal is to find the domain's optimal porosity function that can make the oxygen-hydrogen reaction as uniform as possible. The optimal porosity design ...
C. Trenado, D. Strauss[1,2], and M. Wittmar
Computational Diagnostics & Biocybernetics Unit, Saarland University Hospital, Homburg, Germany
Leibniz-Institute for New Materials, Saarbrücken, Germany
Progress in coating technology has allowed for the development of free-chromate corrosion inhibitors, which are able to smartly migrate when required. In order to support the coating design, we propose a hybrid mathematical model to study the inhibitor's release by taking into account the thermodynamics and kinetics involved in the corrosion process. The proposed model is ...
Keisoku Engineering System Co., Tokyo, Japan
The tertiary current distributions on the wafer in a plating cell are studied in this work. An acid copper sulfate electrolyte composed of CuSO4/5H2O of 2.4 g/L and H2SO4 of 90 g/L is taken into account for copper deposition on the wafer. The solution of shear-plate agitating fluid dynamics is coupled into the calculation of tertiary current distributions. The obtained distributions of tertiary ...
X. Guan, E. Gratz, U. Pal
Division of Materials Science and Engineering, Boston University, Brookline, MA, USA
Computational fluid dynamics (CFD) modeling is a useful tool to gain an insight into various high temperature metallurgical processes such as the magnesium refining and the magnesium solid oxide membrane (SOM) electrolysis. In both processes, argon gas was used to stir the molten salt (flux) in order to improve the transport of magnesium vapor out of the flux and achieve chemical homogeneity in ...
B. Bozzini, S. Maci, I. Sgura, R. Lo Presti, and E. Simonetti
Dipartimento di Ingegneria dell’Innovazione, Università del Salento, Lecce, Italy
Dipartimento di Matematica, Università del Salento, Lecce, Italy
ENEA Casaccia, Dipartimento TER, Centro Ricerche Casaccia, S. Maria di Galeria, Roma, Italy
This paper describes the numerical modeling of a key material-stability issue within the realm of Molten Carbonate Fuel Cells (MCFC). The model describes the morphological and attending electrocatalytic evolution of porous NiO electrodes and is apt to predict electrochemical observables that can be recorded during Fuel Cell operation. The model has been validated with original experimental data ...
R. Coker, J. Mansell
NASA - Marshall Space Flight Center, Huntsville, AL, USA
We have started constructing preliminary design COMSOL models of a bacteriologically driven \'fuel cell\' that is intended to process waste products, such as carbon dioxide and brine, from a crewed vehicle. At this early stage, this complex system is reduced to two electrodes separated by a membrane. The electrolyte is a brine appropriate for growing methanogenic bateria, though none are ...
G. Liebig , G. Gupta , K. Derendorf , C. Agert ,
 DLR Institute of Networked Energy Systems, Oldenburg, Germany
Dedicated work in modeling, simulation and design optimization of Lithium-ion Battery (LIBs) was done in the past decades, and still, the most widely used one for electrochemical processes is the Newman model.  The underlying parameters are treated deterministically, but the impact of uncertainty due to experimental accuracy limitations and cell-to-cell variations have an undeniable impact on ...
Towards the Modeling of Microgalvanic Corrosion in Aluminum Alloys: the Choice of Boundary Conditions
N. Murer, N. Missert, and R. Bucchheit
Fontana Corrosion Center, Ohio State University, Columbus, OH, USA
Sandia National Laboratories, Albuquerque, NM, USA
Aluminum alloys in near-neutral, mildly aggressive solutions, undergo damage accumulation during corrosion, mostly due to the presence of micrometer-sized constituent intermetallic particles (IMP) that create a microstructural discontinuity at which localized corrosion occurs. The Nernst-Planck equation with electroneutrality is used to simulate current and pH distributions resulting from ...
Optimization of the Lithium Insertion Cell with Silicon Negative Electrode for Automotive Applications
R. Chandrasekaran, and A. Drews
Research and Advanced Engineering
Ford Motor Company
The US Advanced Battery Consortium (USABC) has established goals for long term commercialization of advanced batteries for electric vehicle applications. In this work, a dual lithium-ion insertion cell with silicon as the negative electrode and an intercalation material as the positive electrode is modeled using COMSOL Multiphysics. Both are composite porous electrodes with binder, void ...