R. Hamou, P. Biedermann, M. Rohwerder, and A. Blumeneau
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
The present work focuses on modeling a new experimental technique: Scanning Electro-chemical Potential Microscopy (SECPM), which is used to probe the potential profile of the electric double layer (EDL). We used an electrostatic approach to compute the EDL potential measured within the metallic probe. Also, we investigated the effect of the interaction of the electrode/probe double layers on the ...
W. Booth, J. Schiffbauer, J. Fernandez, K. Kelley, A. Timperman, and B. Edwards
Physics Department, West Virginia University, Morgantown, WV, USA
Chemical Engineering Department, West Virginia University, Morgantown, WV, USA
Chemistry Department, West Virginia University, Morgantown, WV, USA
The steady-state non-equilibrium distributions of two species of mono-valent ions around a charged nanofluidic channel have been examined. Large reservoirs were placed on either side of the nanoscale channel to simulate bulk concentration of ions in a fluid. Results from COMSOL Multiphysics simulations show that the effect of the potential bias across the nanochannel yields a significant ...
Optimization of the Lithium Insertion Cell with Silicon Negative Electrode for Automotive Applications
R. Chandrasekaran, and A. Drews
Research and Advanced Engineering
Ford Motor Company
The US Advanced Battery Consortium (USABC) has established goals for long term commercialization of advanced batteries for electric vehicle applications. In this work, a dual lithium-ion insertion cell with silicon as the negative electrode and an intercalation material as the positive electrode is modeled using COMSOL Multiphysics. Both are composite porous electrodes with binder, void ...
Keisoku Engineering System Co., Ltd,. Chiyoda-ku, Tokyo, Japan
The reciprocating paddle cell is a known practical method for depositing alloy films on wafer substrates. Recently, the mass transfer boundary layer within an industrial wafer plating cell was studied based on the measurement of limiting current. It was indicated that a shear-plate fluid agitation mechanism is capable of generating a thin (i.e.
A. Ivanov, U. Mescheder
Furtwangen University, Furtwangen, Germany
In the presented work the dynamic simulation of a silicon anodization process is performed. Two mechanisms of etch form development (diffusion in electrolyte, current flow) are considered and simulated. Influence of electrolyte conductivity and radius of the opening in the masking layer is discussed.
Modeling the Effect of Discrete Distributions of Platinum Particles in the PEM Fuel Cell Catalyst Layer
C.F. Cetinbas, A.K. Prasad, S.G. Advani
Center for Fuel Cell Research, Department of Mechanical Engineering, University of Delaware, Newark, DE, USA
University of Delaware, Newark, DE, USA
In this study, the basic catalyst layer (CL) structure, consisting of carbon-supported Pt particles (C|Pt) and an ionomer binder, is investigated numerically by using COMSOL. The significance of modeling discrete Pt particles on the carbon support is highlighted by comparing the cell performance results to the case in which the Pt is assumed to be distributed uniformly over the carbon support as ...
Department of Chemistry, University of Firenze, Sesto Fiorentino, FI, Italy
Microelectrodes demonstrate that modeling is crucial for understanding the behavior of complex electrochemical systems. The use of the finite element methods in electrochemistry may be of much more general interest for its ability to handle complex geometries. In this context a software such as COMSOL Multiphysics® allows a straightforward way to the set up models including coupling of ...
Kinetic Investigation of a Mechanism for Generating Microstructures on Polycrystalline Substrates Using an Electroplating Process
T. Soares, H. Mozaffari, H. Reinecke
Universität Freiburg, Freiburg im Breisgau, BW, Germany
Hochschule Furtwangen, Tuttlingen, BW, Germany
The purpose of this study is to understand the growth mechanism of copper (Cu) films on a Cu-Zn system substrate with a pre-defined pattern. The pattern was defined by conducting a selective etching process on a two-phase polycrystalline substrate. As a result of this process, there were etched regions correspondent to beta-phase crystals and quasi non-etched regions that belong to alpha-phase ...
Keisoku Engineering System Co., Tokyo, Japan
The tertiary current distributions on the wafer in a plating cell are studied in this work. An acid copper sulfate electrolyte composed of CuSO4/5H2O of 2.4 g/L and H2SO4 of 90 g/L is taken into account for copper deposition on the wafer. The solution of shear-plate agitating fluid dynamics is coupled into the calculation of tertiary current distributions. The obtained distributions of tertiary ...
M. Vallance , A. Meshkov , R. White , M. Guo , S. Rayman , L. Cai 
 GE Global Research, Niskayuna, NY, USA
 R.E. White & Associates, Columbia, SC, USA
Rechargeable batteries solve electrification and communication problems. As examples, hybrid battery-diesel generator power supplies efficiently power cell towers in remote locations, detached from the power grid. Large battery banks are used to load level user power requirements, reducing stress on power generation infrastructure. Batteries firm the output capacity of intermittent wind ...