朱铧丞 , 张春 , 叶菁华 ,
微波作为信息和能量的载体具有同等重要的应用价值，利用微波对物质产生的物理化学效应进行能量传递及转换已经在化学领域有了积极的应用。从 1986 年 R.N. Gedye 等人首次使用微波促进化学反应使其反应速率提高 1240 倍以来，有越来越多的微波和化学领域的科学家对相关问题进行了研究，并出现了一门新兴学科“微波化学”。微波化学作为研究微波能的一个方面是研究微波与化学反应体系相互作用的一个新兴学科。由于当前人们对微波加快化学反应的研究还非常肤浅，微波在大规模应用中并未发挥出其应有的巨大优势，微波化学进一步发展面临着巨大的挑战和机遇。目前微波化学的研究可以分为宏观和微观两个层面：（1）在宏观层面人们并不关心微波对分子之间行为的影响，其研究要用多物理场数值计算方法获得反应体系中电磁场、温度等物理量的分布和变化；（2）微观层面的研究，重点关注微波对反应分子之间相互作用的影响 ...
H. Ishimori, K. Endo, H. Sakanakura, M. Yamada, M. Osako
Ritsumeikan University, Kusatsu, Shiga, Japan
National Institute for Environmental Studies, Tsukuba, Ibaraki Prefecture, Japan
This paper presents the numerical simulation model for radiocesium leaching and transporting behavior in municipal solid waste (MSW) landfill and discusses on the design for the required geometry and properties of the impermeable final cover and the soil sorption layer, which work for containment of hazardous waste such as radiocesium-contaminated MSW generated by Fukushima Daiichi nuclear ...
P. L. Mills, A. Nagaraj
Department of Chemical & Natural Gas Engineering, Texas A&M University, Kingsville, TX, USA
Department of Environmental Engineering, Texas A&M University, Kingsville, TX, USA
Introduction: Development of next-generation chemical processes that have zero emissions is a key environmental objective for sustainable development. The manufacture of H2SO4 by the air oxidation of SO2 to SO3 is an important technology where an opportunity exists for new catalyst development and process innovation by reducing emissions of unconverted SO2 in process reactor tail gases owing to ...
M.K. Ghantasala, B.O. Asimba, A. Khaminwa, K.J. Suthar, D.C. Mancini
Department of Mechanical and Aeronautical Engineering, Western Michigan University, Kalamazoo, MI, USA
Advanced Photon Source, Argonne National Laboratory, Argonne, IL, USA
Physical Sciences and Engineering, Argonne National Laboratory, Argonne, IL, USA
The understanding of pH-sensitive hydrogel swelling response in different buffer environmental condition is essential for its use in different practical applications. This necessitates its simulation in steady state and transient conditions. This paper mainly deals with the details of the numerical simulation performed by developing coupled formulation of chemo-electro-mechanical behavior of ...
A. Warning, A. K. Datta
Department of Biological & Environmental Engineering, Cornell University, Ithaca, NY, USA
Predictive food microbiology currently first requires experimental data for growth on fresh produce and then fitting an empirical or semi-empirical model to the data, making extrapolation to other conditions (temperature, type of produce) difficult. Herein, we develop a mechanistic model for the growth of human pathogenic bacteria (Escherichia coli O157:H7 and Salmonella spp.) on spinach using ...
Study of the CO2 Transfer Rate in a Reacting Flow for the Refined Sodium Bicarbonate Production Process
C. Wylock, A. Larcy, P. Colinet, T. Cartage, and B. Haut
Université Libre de Bruxelles, Brussels, Belgium
Solvay S.A., Brussels, Belgium
This work deals with the quantification of the CO2 transfer rate from a bubble to the surrounding liquid in a bubble column. A model is successfully developed using COMSOL Multiphysics. The validated model is used to study the enhancement influence of chemical reactions on the transfer rate. Moreover, the results of this study are compared with a classical 1-D approach and excellent comparison ...
B. Niu, W. Yan, A.A. Shapiro, and E.H. Stenby
Department of Chemical and Biochemical Engineering, Technical University of Denmark, Kgs. Lyngby, Denmark
As an effective method to cope with green-house gas emission, and to enhance oil recovery, injection of carbon dioxide into oil reservoirs has obtained increasing attentions. The flooding process involves complex phase behavior among oil, brine and CO2, and geochemical reaction between CO2 and rock. COMSOL Multiphysics® was first applied to simulating two flooding processes with known ...
J. Völler, M. Follmann, C. Bayer, and T. Melin
AVT Chemical Process Engineering, RWTH Aachen University, Aachen, Germany
Low temperature fuel cells require hydrogen of high purity for electricity production to avoid catalyst poisoning. To purify hydrogenrich flue gases from hydrocarbon steam reforming membrane shift reactors with a metal membranes may be utilized. A model of a tubular membrane shift reactor with a hydrogenseparating palladium membrane is modeled in the COMSOL Multiphysics® Chemical Engineering ...
J. M. Dedulle , K. Ariyawong , D. Chaussende 
 Univ. Grenoble Alpes, Grenoble, France
 CNRS, Grenoble, France
Silicon carbide (SiC) single crystals are industrially produced by the physical vapor transport technique. Apart from the geometry of the growth setup, there are two main process parameters that can be controlled: temperature and pressure. To support the development of the process, numerical simulation has imposed as the only tool able to describe the process itself, providing a good evaluation ...
K.O. Lund, C.M. Lord
Kurt Lund Consulting, Del Mar, CA, USA
Lord Engineering Corp., Encinitas, CA, USA
Pressure-drop experiments were conducted for the turbulent, compressible flow of air in a small, slender tube, and modeled with COMSOL heat transfer module, and analytically. A scalar integration variable is introduced which integrates the mass velocity [kg/m²s] over the inlet area and iteratively equates this to the input mass flow [kg/s]. For computation, the temperature specification is ...