Soluble Lead-Acid Redox Flow Battery
Application ID: 10023
In a redox flow battery electrochemical energy is stored as redox couples in the electrolyte, which is stored in tanks outside the electrochemical cell. During operation, electrolyte is pumped through the cell and, due to the electrochemical reactions, the individual concentrations of the active species in the electrolyte are changed.
The state of charge of the flow battery is determined by the electrolyte species concentrations, the total flowing electrolyte volume in the system (tank+pump+hoses+cell), and possibly also by the concentration of solid species on the electrodes. Depending on the cell chemistry the cell can have separated or combined anode and cathode compartments and electrolyte tanks.
This model simulates a soluble lead-acid flow battery during an applied charge-discharge load cycle. The surface chemistry of the positive electrode is modeled by using two different lead oxides and two different positive electrode reactions in the model.
This model example illustrates applications of this type that would nominally be built using the following products:
however, additional products may be required to completely define and model it. Furthermore, this example may also be defined and modeled using components from the following product combinations:
- COMSOL Multiphysics® and
- either the Corrosion Module, Electrochemistry Module, or Electrodeposition Module
The combination of COMSOL® products required to model your application depends on several factors and may include boundary conditions, material properties, physics interfaces, and part libraries. Particular functionality may be common to several products. To determine the right combination of products for your modeling needs, review the Specification Chart and make use of a free evaluation license. The COMSOL Sales and Support teams are available for answering any questions you may have regarding this.